| Round 1 |
| | Pavel Andrei Schuettler Rainer | 6, 4, 6, 3, 7 2, 6, 3, 6, 5 | December 22, 2022 | 0 |
| | Mirnyi Max Kucera Karol | 2, 6, 6, 4, 7 6, 3, 0, 6, 5 | December 21, 2022 | 0 |
| | Sa Andre Vacek Jan | Forfeit | December 21, 2022 | 0 |
| | Philippoussis Mark Diaz Jacobo | 7, 7, 4, 6 6, 6, 6, 3 | December 21, 2022 | 0 |
| | Arthurs Wayne Robredo Tommy | 6, 6, 6 3, 2, 2 | December 21, 2022 | 0 |
| | Ferrero Juan Carlos Koubek Stefan | 6, 6, 4, 7 3, 4, 6, 5 | December 21, 2022 | 0 |
| | Agassi Andre Safin Marat | 6, 6, 6 3, 4, 0 | December 21, 2022 | 0 |
| | Kratochvil Michel Lee Martin | Forfeit | December 21, 2022 | 0 |
| | Ljubicic Ivan Bastl George | 6, 4, 6, 6 2, 6, 4, 2 | December 21, 2022 | 0 |
| | Rusedski Greg Dupuis Antony | 6, 6, 2, 4, 6 1, 4, 6, 6, 2 | December 21, 2022 | 0 |
| | Moya Carlos Woodruff Chris | 7, 7, 6, 6 5, 5, 7, 3 | December 20, 2022 | 0 |
| | Vinciguerra Andreas El Aynaoui Younes | 7, 4, 6, 5, 7 5, 6, 0, 7, 6 | December 20, 2022 | 0 |
| | Canas Guillermo Boutter Julien | 6, 6, 6 3, 3, 3 | December 20, 2022 | 0 |
| | Delgado Ramon Nieminen Jarkko | Forfeit | December 20, 2022 | 0 |
| | Voinea Adrian Savolt Attila | Forfeit | December 20, 2022 | 0 |
| | Vanek Jiri Blake James | Forfeit | December 20, 2022 | 0 |
| | Tabara Michal Malisse Xavier | Forfeit | December 20, 2022 | 0 |
| | Henman Tim Van Scheppingen Dennis | 6, 6, 6 4, 3, 1 | December 20, 2022 | 0 |
| | Van Lottum John Lopez Marc | Forfeit | December 20, 2022 | 0 |
| | Gustafsson Magnus Gaudenzi Andrea | 6, 6, 1, 6 4, 3, 6, 4 | December 19, 2022 | 0 |
| | Clavet Francisco Clement Arnaud | 6, 5, 3, 6, 7 3, 7, 6, 2, 5 | December 19, 2022 | 0 |
| | Ferreira Wayne Russell Michael | 6, 6, 7 2, 2, 6 | December 19, 2022 | 0 |
| | Mamiit Cecil Labadze Irakli | Forfeit | December 19, 2022 | 0 |
| | Hrbaty Dominik Arazi Hicham | 2, 6, 6, 6 6, 3, 0, 0 | December 19, 2022 | 0 |
| | Kiefer Nicolas Sanchez David | 6, 6, 3, 6, 6 2, 0, 6, 7, 3 | December 19, 2022 | 0 |
| | Portas Albert Grosjean Sebastien | 6, 6, 6 3, 3, 3 | December 19, 2022 | 0 |
| | Gambill Jan Michael Panatta Adriano | 6, 6, 6 3, 0, 1 | December 19, 2022 | 0 |
| | Burgsmuller Lars Simoni Alexandre | Forfeit | December 19, 2022 | 0 |
| | Kuerten Gustavo Rochus Christophe | 6, 6, 6 0, 4, 3 | December 19, 2022 | 0 |